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🎲 Introduction to Classical Statistical Mechanics

Classical Statistical Mechanics for Materials Science

📚 5 Chapters 💻 35 Code Examples ⏱️ 100-120 minutes 📊 Intermediate
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🎯 Series Overview

Classical statistical mechanics is a theoretical framework for understanding the thermodynamic properties of material systems consisting of many particles from a microscopic perspective. In this series, you will learn the theory of microcanonical, canonical, and grand canonical ensembles, partition functions, free energy, the statistical mechanical description of phase transitions, and implement statistical mechanics simulations such as Monte Carlo methods using Python.

Learning Path

flowchart LR A[Chapter 1
Ensembles] B[Chapter 2
Partition Functions] C[Chapter 3
Free Energy] D[Chapter 4
Monte Carlo] E[Chapter 5
Materials Applications] A --> B --> C --> D --> E style A fill:#667eea,stroke:#764ba2,stroke-width:2px,color:#fff style B fill:#667eea,stroke:#764ba2,stroke-width:2px,color:#fff style C fill:#667eea,stroke:#764ba2,stroke-width:2px,color:#fff style D fill:#667eea,stroke:#764ba2,stroke-width:2px,color:#fff style E fill:#667eea,stroke:#764ba2,stroke-width:2px,color:#fff

📋 Learning Objectives

  • Understand the theory of statistical ensembles (microcanonical, canonical, and grand canonical)
  • Derive thermodynamic quantities from partition functions
  • Understand the relationship between free energy and phase equilibrium
  • Understand and implement lattice models such as the Ising model
  • Perform statistical mechanics simulations using Monte Carlo methods

📖 Prerequisites

You can learn this material with basic knowledge of thermodynamics and probability theory. It is desirable to have a basic understanding of Python usage.

Chapter 1
Statistical Ensembles and Entropy

We learn the concepts of phase space and microstates, the principle of equal a priori probability, and the definition of the microcanonical ensemble. We derive Boltzmann's entropy formula and calculate the entropy and equation of state of an ideal gas using Python.

Phase Space Microcanonical Ensemble Principle of Equal Probability Boltzmann Entropy Ideal Gas Stirling's Approximation
💻 7 Code Examples ⏱️ 20-24 minutes
Read Chapter 1 →
Chapter 2
Canonical Ensemble and Partition Function

We learn the definition of the canonical ensemble, the canonical partition function, and Helmholtz free energy. We derive internal energy, entropy, and heat capacity from the partition function, and implement harmonic oscillator systems and the Einstein solid model using Python.

Canonical Ensemble Canonical Partition Function Helmholtz Free Energy Equipartition Theorem Harmonic Oscillator Einstein Solid
💻 7 Code Examples ⏱️ 20-24 minutes
Read Chapter 2 →
Chapter 3
Grand Canonical Ensemble and Chemical Potential

We learn the definition of the grand canonical ensemble, the grand partition function, and the concept of chemical potential. We derive the grand partition function for an ideal gas and implement adsorption isotherms (Langmuir adsorption) and the lattice gas model using Python.

Grand Canonical Ensemble Grand Partition Function Chemical Potential Particle Number Fluctuations Langmuir Adsorption Lattice Gas
💻 7 Code Examples ⏱️ 20-24 minutes
Read Chapter 3 →
Chapter 4
Ideal Gas and Quantum Statistics

We derive the Maxwell velocity distribution for classical ideal gases and learn the basics of quantum statistics (Fermi-Dirac distribution, Bose-Einstein distribution). We calculate the Planck distribution for photon gas and the density of states for Fermi electron systems using Python.

Maxwell Velocity Distribution Fermi-Dirac Distribution Bose-Einstein Distribution Planck Distribution Fermi Electrons Bose Condensation
💻 7 Code Examples ⏱️ 20-24 minutes
Read Chapter 4 →
Chapter 5
Lattice Models and Monte Carlo Methods

We learn the theory of the Ising model (mean-field approximation, critical phenomena) and implement the Metropolis Monte Carlo method algorithm. Through simulation of the 2D Ising model, we calculate phase transitions and critical exponents using Python.

Ising Model Mean-Field Approximation Metropolis Method Monte Carlo Method Phase Transition Critical Exponents
💻 7 Code Examples ⏱️ 20-24 minutes
Read Chapter 5 →

📚 Recommended Learning Paths

Pattern 1: Beginner - Theory and Practice Balanced (5-7 days)

Pattern 2: Intermediate - Fast Track (3 days)

Pattern 3: Topic-Focused - Computational Skills (1 day)

🎯 Overall Learning Outcomes

Upon completing this series, you will achieve:

Knowledge Level

Practical Skills

Application Ability

🛠️ Technologies and Tools Used

Main Libraries

Development Environment

Recommended Tools

🚀 Next Steps

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